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Poly(vinyl chloride), commonly
abbreviated PVC, is the third-most widely produced polymer,
after polyethylene and polypropylene. PVC is used in construction because
it is more effective than traditional materials such as copper, iron or wood in
pipe and profile applications. It can be made softer and more flexible by the
addition of plasticizers, the most widely used being phthalates. In
this form, it is also used in plumbing, electrical cable insulation, inflatable
products and many applications where it replaces rubber.
Pure poly(vinyl chloride) is a white,
brittle solid. It is insoluble in alcohol, but slightly soluble in tetrahydrofuran.
Mechanical properties
PVC has high hardness and mechanical
properties. The mechanical properties enhance with the molecular weight
increasing, but decrease with the temperature increasing. The mechanical
properties of rigid PVC (uPVC) are very good, the elastic modulus can reach to
1500-3,000 MPa. The soft PVC (Flexible PVC) elastic is 1.5-15 MPa. However,
elongation at break is up to 200% -450%. PVC friction is ordinary, the static
friction factor is 0.4-0.5, the dynamic friction factor is 0.23.
Thermal properties
The heat stability of PVC is very poor,
when the temperature reaches 140 °C PVC starts to decompose. Its melting
temperature is 160 °C. The linear expansion coefficient of the PVC is small and
has flame retardancy, the oxidation index is up to 45 or more. Therefore, the
addition of a heat stabilizer during the process is necessary in order to
ensure the product's properties.
Electrical properties
PVC is a polymer with good insulation
properties but because of its higher polar nature the electrical insulating property
is inferior to non-polar polymers such as polyethylene and polypropylene.